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Net present value optimization of a natural gas combined cycle plant with CO2 capture using a water-lean solvent considering transient electricity price for multiple regions
Haque, M. E., Summits, S., Giridhar, N., Ijiyinka, I., Le, Q. M., Zhang, Z., Mobley, P. D., Gupta, V., Jiang, Y., Freeman, C., Heldebrant, D. J., Omell, B. P., Swisher, J., Matuszewski, M., de Mello, P., & Bhattacharyya, D. (2025). Net present value optimization of a natural gas combined cycle plant with CO2 capture using a water-lean solvent considering transient electricity price for multiple regions. Industrial & Engineering Chemistry Research, 64(47), 22790-22812. https://doi.org/10.1021/acs.iecr.5c02872
Global CO2 emissions are increasing at about a 1.5% rate per year. Fossil fuel-based plants are one of the main contributors to this rise. In the power generation industry, fossil fuel plants are dominant, and many plants are under development. In this study, a natural gas combined cycle (NGCC) power plant with postcombustion capture using a leading water-lean solvent is considered. For optimal design and operating schedule, large-scale dynamic optimization is undertaken for net present value (NPV) optimization. The first principle dynamic model of NGCC is developed, including a model of the highly efficient H-class gas turbines. For computational tractability of the dynamic optimization problem, a reduced-order model is developed by using the Hankel singular value decomposition. A water-lean solvent, N-(2-ethoxyethyl)-3-morpholinopropan-1-amine, is used for carbon capture. A model of the capture system is developed in Aspen Plus, which is used to develop a reduced-order model by using ALAMO, a machine learning software. In addition, a reduced model of the CO2 compression system with a dehydration unit is also considered. The integrated system is used for NPV optimization by using the Python-based PYOMO platform. The PCC process is analyzed for three configurations-conventional packed bed, rotating packed bed (RPB), and a combination of RPB and direct contact cooler. The NPV optimization is performed for 14 regional markets by considering year-long clustered and continuous locational marginal price data with a 1 h interval. Optimization results show that the PCC can achieve 90% CO2 capture with a positive NPV for six regions. Sensitivity studies conducted by using the PCC configurations indicate that the process is economically feasible for 9 regions out of 14 regional electricity markets with NPV values in the range of 33–540 $MM.
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